

Cementitious Calorimetry
An investigation into the thermal properties of Corex slag and the relationship between thermal profiles and setting times
Kyle Cullen van der Westhuizen - 4th year Dissertaion - CIV4044S
It is nearly impossible to conduct “perfect” adiabatic calorimetry tests without specialised equipment, which may be costly in most cases. A hybrid termed semi-adiabatic calorimetry is thus employed frequently to describe a simple more cost effective means by which to measure the heat of hydration. Semi-adiabatic calorimetry can be described as an indication of the heat evolved from a cementitious mixture hydrating in an environment or container having some thermal insulation properties, according to a record of the mixture’s changing temperatures over time.
The properties of a semi-adiabatic calorimeter are as follows:
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The value is generally in comparative data
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Simpler, less expensive equipment is required
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Results are affected by certain variables
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Useful in the field or the laboratory
Simple semi-adiabatic calorimeters can be constructed on relatively low budgets for use in the field or in the lab for many practical applications and can be used for the following applications:
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Comparing setting time effects and hydration efficiency
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Troubleshooting concrete field problems
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Cement quality control (optimizing sulphate content)
A simple semi-adiabatic calorimeter constructed using thermocouples (temperature senors) and polystyrene cups (insulation) can be seen in the figure below.
SEMI-ADIABATIC CALORIMETRY
